In all the yurts I've stayed in, I've not noticed any sort of offgassing. The canvas is impregnated, and the panel windows are poly (which could be done with glass windows if the strucutre was going to be more permanent). I believe there are far less volatiles coming off the Yurt than my wood built home (carpeting, varnish, tile sealant, window sealant, paint, and various cleaning agents are all volatilistic and common in most stick built homes these days).
My canvas wall tent was always chemically smelly, even after repeated uses and washdowns. It was flame resistant and waterproof, so I guess you make compromises.
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The ultimate result of shielding men from the effects of folly is to fill the world with fools.
-- Herbert Spencer, English Philosopher (1820-1903)