I've used NikWax to do a really nice waterproofing job on an old 60/40 shell I have.  (How many here are old enough to remember 60/40???)  I was amazed at how well it worked. Water beaded right up on that 30+ year old shell. I tested it with a yard hose and nozzle.  Stayed 99% dry after a good 10 second full force burst of water.  Real life tests have been limited to light drizzle, but it came through that perfectly (as expected).  I used the NikWax variety that you dump into the washing machine, not the spray-on kind.
In a massive hours long downpour I'd probably trust one of my newer waterproof-breathables to keep me dry, excepting sweat, but short of hurricane conditions I actually prefer the breathability and soft comfort of that old 60/40/NikWax thing.  "Waterprrof-breathable" is a great marketing term and concept, yet to be achieved in reality.  "More breathable than a trashbag" - yes, more breathable than 60/40/NikWax - no.  All that being said, I typically take my new wiz-bang shell along rather than my old 60/40 on hikes if there's significant chance of heavy rain.  It's smaller and lighter.  I'm a hypocrit ... what can I say?!