The reason for carrying pocket gear is three fold.
First is time.
Sure I can start a fire by rubbing 2 Boy Scouts together. Standard primitive skills training. Scenario I just fell through the ice. I'm soaking wet and my cloths are freezing stiff. The seconds or minutes between using a match or lighter versus constructing a bow drill and getting the fire going. That little bit of time could mean the difference. So gear buys you the time it takes to make the tool to make the tool you need.
Second is quality.
Sure I can make a cutting implement from the things I could find around me. But a steel knife blade works a lot better and lasts longer.
Third is confidence.
If TSHTF tell me you will not feel more self assured just knowing that the gear is available. That alone may make the problem smaller. At least in your mind and therefore easier to over come. Remember panic can kill you quicker than just about anything else. Just the time of breaking open a kit puts your mind in survival mode thinking. It keys your thinking from the situation back to your training.
By this do I mean forget learning primitive skills HE Double hockey sticks NO!!!
The skills are a great back up if your gear is lost, damaged or inadequate. Also if things last longer than expected they can improve your lot in the situation. Is gear the end all be all. No. You can only carry so much. How you use it, the skills to use it and the ability to make what you need from what is available is how you survive.
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When in danger or in doubt
run in circles scream and shout
RAH
And always remember TANSTAAFL