I see a lot of people drawing up and out, pointing the muzzle into their hip. Far worse is when people holster- very often they stuck the gun into their hip and wedge it into the holster! Not good.
At any rate, with the chest rig I unzip the pack with my left, get a firing grip on the sidearm (finger outside the trigger guard along the frame/slide of the gun) and pull back, up, and out while rotating the the gun forward (kind of like backing out of a parking space). This way you never cover yourself with the muzzle.
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“I'd rather have questions that cannot be answered than answers that can't be questioned.” —Richard Feynman