I would collect all the glass or plastic sheets I can find, and build a long narrow room with lots and lots of glass surface.
I'm curious, Chisel, do you have sort of idea of how much water you could produce for your mega solar still idea? I'm always disappointed at how little solar stills produce, and I wouldn't be surprised if scaling it up even much larger still yields a pretty meager amount of water.
You would probably net a whole lot more potable water by going out and finding bottled water, or even draining water heaters. One big, commercial water heater could last quite a while. Security may be an issue with going out, but even at "the colony" they still had to worry about outsiders breaking in, so even a solar still inside your compound could make a juicy target that needs a lot of resources to defend, especially if word of its existence gets around. Anyway, just some musings.