Contact your local Fire Prevention office of your local Fire Department for training opportunities.
That is likely the best advice of all.
If you look at industrial sites you will notice most fire extinguishers are located at the exits. The idea is to get people out of the building instead of letting them be trapped inside by the fire.
Most people do not have the training or skills to fight a fire effectively.
Usually they panic and do exactly the wrong things.
The first step in being prepared is to get the required knowledge.
(and firefighting really should include fire prevention as a first step)
Edit: Roarmeister, how often do you change the batteries in your alarm? (LOL)