When it comes to 'grippy' other than Converse Hi-Tops, I have to swear by Red Wings whatever-they-call-them (for certain things, at least):
http://www.redwingshoes.com/productdetails.aspx?prodid=1156In a few years of trolling around old-school underground mines (not caves, mind you - walking level-ish ground, climbing ladders, etc) they've been the best in both of terms of wearability and comfort...and the comfort is comparable to a new (not broken-in) running shoe. Pretty good for a boot.
Since I can't recall (find) a model number, the instep says "Oil-Resistant Long-Wearing Non-Marking Urethane." It really feels like a gum sole. Highly recommended, and also by a compatriot.
I realize this is the second of my posts extolling the virtues of Red Wings; they've never done me wrong, but the guys with Whites have complained more about their feet than anybody else. Not that White makes a bad boot but if you're going to complain about something, it doesn't matter what you're carrying / wearing. Personality issue.
Anyway, disclaimer disclaimer.