I don't buy the argument that synthetics are all hype and marketing. Synthetics are the proven winner for the self-propelled traveller who doesn't have the option to jump in a truck and dry out. They're also good value because they last and last.
I agree. I came into synthetics the summer route, when I started road cycling in '98. I started out in the summer, riding in shorts & cotton T-shirts. Now this is Texas, so I always came back completely soaked through. I always thought the cycling spandex look was kind of ridiculous, so I resisted it for the longest time. Then I started going out with one of the local bike clubs, and learned that the stuff was about heat control and aerodynamics more than look. So, I bit the bullet and got a synthetic jersy and shorts. Can't say I was dry, but airflow over it ensured that I was only damp instead of soaked through. This was true even during the Hotter than Hell 100 mi ride, with temps peaking at 107 degrees. Never had a heat injury either.
Can't speak for it in winter, since you're covering the synthetic with something that keeps the air off it, but for summer heavy activity, I'm a convert.